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Technical Paper

Neat Biodiesel Fuel Engine Tests and Preliminary Modelling

2007-04-16
2007-01-0616
Engine performance and emission comparisons were made between the use of 100% soy, Canola and yellow grease derived biodiesel fuels and an ultra-low sulphur diesel fuel in the oxygen deficient regions, i.e. full or high load engine operations. Exhaust gas recirculation (EGR) was extensively applied to initiate low temperature combustion. An intake throttling valve was implemented to increase the differential pressure between the intake and exhaust in order to increase and enhance the EGR. The intake temperature, pressure, and EGR levels were modulated to improve the engine fuel efficiency and exhaust emissions. Furthermore, a preliminary ignition delay correlation under the influence of EGR was developed. Preliminary low temperature combustion modelling of the biodiesel and diesel fuels was also conducted. The research intends to achieve simultaneous reductions of nitrogen oxides and soot emissions in modern production diesel engines when biodiesel is applied.
Technical Paper

Detailed Diesel Exhaust Particulate Characterization and DPF Regeneration Behavior Measurements for Two Different Regeneration Systems

2007-04-16
2007-01-1063
Three distinct types of diesel particulate matter (PM) are generated in selected engine operating conditions of a single-cylinder heavy-duty diesel engine. The three types of PM are trapped using typical Cordierite diesel particulate filters (DPF) with different washcoat formulations and a commercial Silicon-Carbide DPF. Two systems, an external electric furnace and an in-situ burner, were used for regeneration. Furnace regeneration experiments allow the collected PM to be classified into two categories depending on oxidation mechanism: PM that is affected by the catalyst and PM that is oxidized by a purely thermal mechanism. The two PM categories prove to contribute differently to pressure drop and transient filtration efficiency during in-situ regeneration.
Technical Paper

Simultaneous Real-Time Measurements of NO and NO2 in Medium Duty Diesel Truck Exhaust

2007-04-16
2007-01-1329
The goal of the present work was to investigate the ability of the SEMTECH®-D Portable Emissions Measurement System (PEMS) to provide simultaneous, accurate, real-time (1Hz) measurements of NO and NO2 in vehicle exhaust. Extensive chassis dynamometer laboratory evaluation studies of the SEMTECH® system were conducted. The instantaneous (1Hz) NOx emissions were measured using a conventional chemiluminescence analyzer (CLA) and were compared to the sum of the instantaneous NO and NO2 measurements from the SEMTECH®-D. The sum of the NO and NO2 emissions measured by the SEMTECH® were in excellent agreement (within 95% in most cases) with the total NOx measurements from the conventional CLA. During the laboratory evaluation studies, several Federal Test Procedure (FTP) drive cycles were conducted. Examples of the NO and NO2 concentration and mass emissions measured using the SEMTECH®-D are presented along with the corresponding SEMTECH®-D detection limits.
Technical Paper

Laboratory Studies and Mathematical Modeling of Urea SCR Catalyst Performance

2007-04-16
2007-01-1573
This paper presents the development of an analytical model that complements laboratory based experiments to provide a tool for Selective Catalyst Reduction (SCR) applications. The model calibration is based on measured data from NOx reduction performance tests as well as ammonia (NH3) adsorption/desorption tests over select SCR catalyst formulations in a laboratory flow reactor. Only base metal/zeolite SCR samples were evaluated. Limited validations are presented that show the model agrees well with vehicle data from Environmental Protection Agency Federal Test Procedure (EPA FTP) emission assessments. The model includes energy and mass balances, several different NH3 reactions with NOx, NH3 adsorption and desorption algorithms, and NH3 oxidation.
Technical Paper

The Influence of Ammonia Slip Catalysts on Ammonia, N2O and NOX Emissions for Diesel Engines

2007-04-16
2007-01-1572
The use of urea-based selective catalytic reduction (SCR) is a promising method for achieving U.S. Tier 2 diesel emission standards for NOx. To meet the Tier 2 standards for Particulate Matter (PM), a catalyzed diesel particulate filter (CDPF) will likely be present and any ammonia (NH3) that is not consumed over an SCR catalyst would pass over the CDPF to make nitrous oxide (N2O) emissions and/or oxides of nitrogen (NOx), or exit the exhaust system as NH3. N2O is undesirable due to its high greenhouse gas potential, while NOx production from the slipped NH3 would reduce overall system NOx conversion efficiency. This paper reviews certain conditions where NH3 slip past an SCR system may be a concern, looks at what would happen to this slipped NH3 over a CDPF, and evaluates the performance of various supplier NH3 slip catalysts under varied space velocities, temperatures and concentrations of NH3 and NOx.
Technical Paper

The Influence of Ammonia to NOX Ratio on SCR Performance

2007-04-16
2007-01-1581
It is likely that use of urea-based selective catalytic reduction (SCR) will be needed to meet U.S. Tier 2 diesel emission standards for oxides of nitrogen (NOx). The ideal ratio of ammonia (NH3) molecules to NOx molecules (known as alpha) is 1:1 based on urea consumption and having NH3 available for reaction of all of the exhaust NOx. However, SCR efficiency can be less than 100% at low temperatures in general, and at higher temperatures with high exhaust SCR catalyst space velocities. At the low temperatures where NOx conversion efficiency is low, it may be advantageous to reduce the alpha ratio to values less than one (less NH3 than is needed to convert 100% of the NOx emissions) to avoid NH3 slip. At higher space velocities and high temperatures, the NOx conversion efficiency may be higher with alpha ratios greater than 1. There is however concern that the additional NH3 will be slipped under these conditions.
Technical Paper

Cranktrain Design for Ford's HEV DI Diesel Engine

1998-08-11
981915
This paper focuses on the cranktrain design for Ford's HEV DI Diesel Engine called the DIATA. The design started with the piston pin. The minimum piston pin diameter for the lowest reciprocation weight was achieved by tapering the small end of the connecting rod. Geometry constraints sized the connecting rod's big end diameter, oil film analyses determined the width, and an FEA verified the design. Next, the crankshaft mains were sized to reach an acceptable factor of safety, bending and torsional stiffness, and oil films. Finally, the flywheel was sized to be the minimum weight to reduce transmission gear rattle to an acceptable level.
Technical Paper

Analytical Life Prediction Modelling of an Automotive Timing Belt

2008-04-14
2008-01-1207
This paper presents a methodology that makes use of computer based analytical simulation methods combined with statistical tools to predict timing belt life. This allows timing belt life to be estimated with no requirement for running test engines and associated test equipment, which is both very time and expense exhaustive. A case study on a belt driven primary drive for a V6 Diesel engine was used to illustrate the methodology. A computer based dynamic model for the belt drive system was developed and validated, and a belt life prediction model was developed, which uses tooth load predictions from the analytical model. Statistical modeling of predicted damage accumulated to failure was used to estimate the model parameters given a limited set of belt life results from a motored rig test. The practical use of the model is illustrated by predicting belt life under customer usage.
Technical Paper

1-D Modeling of Transient Engine Operations Using Data Generated by a CFD Code

2008-04-14
2008-01-0357
Transient engine operations are modeled and simulated with a 1-D code (GT Power) using heat release and emission data computed by a 3-D CFD code (Kiva3). During each iteration step of a transient engine simulation, the 1-D code utilizes the 3-D data to interpolate the values for heat release and emissions. The 3-D CFD computations were performed for the compression and combustion stroke of strategically chosen engine operating points considering engine speed, torque and excess air. The 3-D inlet conditions were obtained from the 1-D code, which utilized 3-D heat release data from the previous 1-D unsteady computations. In most cases, only two different sets of 3-D input data are needed to interpolate the transient phase between two engine operating points. This keeps the computation time at a reasonable level. The results are demonstrated on the load response of a generator which is driven by a medium-speed diesel engine.
Technical Paper

Adaptive EGR Cooler Pressure Drop Estimation

2008-04-14
2008-01-0624
The pre EGR valve pressure is an important measurement for the Diesel engine air handling system. It is commonly used for the EGR flow calculation during engine transient operation. Due to the erosive exhaust gas, an EGR pressure sensor will eventually have gold corrosion resulting in drive-ability issues. Therefore, a software replacement for the EGR pressure sensor is desirable. However, when the EGR valve is on the cold side of the EGR cooler, the accuracy of the EGR pressure estimation deteriorates because of the variability of the pressure drop across the EGR cooler due to EGR cooler fouling. In this paper, an adaptive scheme is developed to improve the accuracy of pre EGR valve pressure estimation in the presence of EGR cooler fouling for diesel engines. The pressure drop across the EGR cooler is shown to be proportional to the velocity pressure of the EGR flow through the cooler.
Technical Paper

Influence of Hydrocarbon Storage on the Durability of SCR Catalysts

2008-04-14
2008-01-0767
Selective catalytic reduction (SCR) is a technology capable of meeting Tier 2 Bin 5 emissions levels of oxides of nitrogen (NOX) for diesel engines. Base metal zeolite catalysts show the best combination of thermal durability and NOX conversion activity. It is shown in this work that some base metal zeolite catalysts can store high levels of hydrocarbons (HCs). Also, base metal zeolite catalysts can catalyze oxidation of HCs under certain conditions. Oxidation of stored hydrocarbons can lead to permanent catalyst deactivation due to the exotherm generated in the SCR catalyst (over-temperature condition leading to SCR catalyst damage). This paper discusses a laboratory bench test to characterize hydrocarbon storage and burn-off characteristics of several SCR catalyst formulations, as well as engine dynamometer tests showing hydrocarbon storage and exotherm generation.
Technical Paper

Optimization of an Asynchronous Fuel Injection System in Diesel Engines by Means of a Micro-Genetic Algorithm and an Adaptive Gradient Method

2008-04-14
2008-01-0925
Optimal fuel injection strategies are obtained with a micro-genetic algorithm and an adaptive gradient method for a nonroad, medium-speed DI diesel engine equipped with a multi-orifice, asynchronous fuel injection system. The gradient optimization utilizes a fast-converging backtracking algorithm and an adaptive cost function which is based on the penalty method, where the penalty coefficient is increased after every line search. The micro-genetic algorithm uses parameter combinations of the best two individuals in each generation until a local convergence is achieved, and then generates a random population to continue the global search. The optimizations have been performed for a two pulse fuel injection strategy where the optimization parameters are the injection timings and the nozzle orifice diameters.
Technical Paper

Influence of Spray-Wall Interaction and Fuel Films on Cold Starting in Direct Injection Diesel Engines

1998-10-19
982584
Various single and split injection schemes are studied to provide a better understanding of fuel distribution during cold starting in DI diesel engines. Improved spray-wall interaction, fuel film and multicomponent vaporization models are used to analyze the combustion processes. Better combustion characteristics are obtained for the split injection schemes than with a single injection. An analysis of the fuel impingement processes identifies the mechanisms involved in producing the differences in vaporization and combustion of the fuel. A greater amount of splashing occurred for the split injections compared to a single injection. This behavior is attributed to the decreased film thickness (less dissipation of impingement energy), the decreased impingement area (obtained by increasing the impingement Weber number), and most importantly, the reduced frequency of drop impingement.
Technical Paper

The Effect of Dimethoxy Methane Additive on Diesel Vehicle Particulate Emissions

1998-10-19
982572
FTP emissions tests on a passenger vehicle equipped with a 1.8 L IDI turbo-charged diesel engine show that the mass emissions of particles decrease by (36±8)% when 16.6% dimethoxymethane (DMM) by volume is added to a diesel fuel. Particle size measurements reveal log-normal accumulation mode distributions with number weighted geometric mean diameters in the 80 - 100 nm range. The number density is comparable for both base fuel and the DMM/diesel blend; however, the distributions shift to smaller particle diameter for the blend. This shift to smaller size is consistent with the observed reduction in particulate mass. No change is observed in NOx emissions. Formaldehyde emissions increase by (50±25)%, while emissions of other hydrocarbons are unchanged to within the estimated experimental error.
Technical Paper

Comparison of Analytically and Experimentally Obtained Residual Fractions and NOX Emissions in Spark-Ignited Engines

1998-10-19
982562
Using a fast-sampling valve, residual-fraction levels were determined in a 2.0L spark-ignited production engine, over varying engine operating conditions. Individual samples for each operating condition were analyzed by gas-chromatography which allowed for the determination of in-cylinder CO and CO2 levels. Through a comparison of in-cylinder measurement and exhaust data measurements, residual molar fraction (RMF) levels were determined and compared to analytical results. Analytical calculations were performed using the General Engine SIMulation (GESIM) which is a steady state quasi-dimensional engine combustion cycle simulation. Analytical RMF levels, for identical engine operating conditions, were compared to the experimental results as well as a sensitivity study on wave-dynamics and heat transfer on the analytically predicted RMF. Similarly, theoretical and experimental NOx emissions were compared and production sensitivity on RMF levels explored.
Technical Paper

Modeling of Soot Formation During DI Diesel Combustion Using a Multi-Step Phenomenological Model

1998-10-19
982463
Predictive models of soot formation during Diesel combustion are of great practical interest, particularly in light of newly proposed strict regulations on particulate emissions. A modified version of the phenomenological model of soot formation developed previously has been implemented in KIVA-II CFD code. The model includes major generic processes involved in soot formation during combustion, i.e., formation of soot precursors, formation of surface growth species, soot particle nucleation, coagulation, surface growth and oxidation. The formulation of the model within the KIVA-II is fully coupled with the mass and energy balances in the system. The model performance has been tested by comparison with the results of optical in-cylinder soot measurements in a single cylinder Cummins NH Diesel engine. The predicted soot volume fraction, number density and particle size agree reasonably well with the experimental data.
Technical Paper

Verification of Accelerated PM Loading for DPF Qualification Studies

2009-04-20
2009-01-1089
High gas prices combined with demand for improved fuel economy have prompted increased interest in diesel engine applications for both light-duty and heavy-duty vehicles. The development of aftertreatment systems for these vehicles requires significant investments of capital and time. A reliable and robust qualification testing procedure will allow for more rapid development with lower associated costs. Qualification testing for DPFs has its basis in methods similar to DOCs but also incorporates a PM loading method and regeneration testing of loaded samples. This paper examines the effects of accelerated loading using a PM generator and compares PM generator loaded DPFs to engine dynamometer loaded samples. DPFs were evaluated based on pressure drop and regeneration performance for samples loaded slowly and for samples loaded under accelerated conditions. A regeneration reactor was designed and built to help evaluate the DPFs loaded using the PM generator and an engine dynamometer.
Technical Paper

Development of Emission Transfer Functions for Predicting the Deterioration of a Cu-Zeolite SCR Catalyst

2009-04-20
2009-01-1282
Urea selective catalytic reduction (SCR) catalysts have the capability to deliver the high NOx conversion efficiencies required for future emission standards. However, the potential for the occasional over-temperature can lead to the irreversible deactivation of the SCR catalyst. On-board diagnostics (OBD) compliance requires monitoring of the SCR function to make sure it is operating properly. Initially, SCR catalyst performance metrics such as NOx conversion, NH3 oxidation, NH3 storage capacity, and BET surface area are within normal limits. However, these features degrade with high temperature aging. In this work, a laboratory flow reactor was utilized to determine the impact on these performance metrics as a function of aging condition. Upon the completion of a full time-at-temperature durability study, four performance criteria were established to help determine a likely SCR failure.
Technical Paper

Operating a Heavy-Duty Direct-Injection Compression-Ignition Engine with Gasoline for Low Emissions

2009-04-20
2009-01-1442
A study of partially premixed combustion (PPC) with non-oxygenated 91 pump octane number1 (PON) commercially available gasoline was performed using a heavy-duty (HD) compression-ignition (CI) 2.44 l Caterpillar 3401E single-cylinder oil test engine (SCOTE). The experimental conditions selected were a net indicated mean effective pressure (IMEP) of 11.5 bar, an engine speed of 1300 rev/min, an intake temperature of 40°C with intake and exhaust pressures of 200 and 207 kPa, respectively. The baseline case for all studies presented had 0% exhaust gas recirculation (EGR), used a dual injection strategy a -137 deg ATDC pilot SOI and a -6 deg ATDC main start-of-injection (SOI) timing with a 30/70% pilot/main fuel split for a total of 5.3 kg/h fueling (equating to approximately 50% load). Combustion and emissions characteristics were explored relative to the baseline case by sweeping main and pilot SOI timings, injection split fuel percentage, intake pressure, load and EGR levels.
Technical Paper

Cu/Zeolite SCR on High Porosity Filters: Laboratory and Engine Performance Evaluations

2009-04-20
2009-01-0897
Selective catalytic reduction (SCR) is expected to be used extensively in the U.S. for diesel vehicle NOx control. Much progress has been made on improving performance and reducing complexity of SCR systems for vehicles in the past several years. SCR system complexity can be reduced further by implementation of SCR-coated diesel particulate filters (SCRFs). In this system, a high porosity (> 50%) filter substrate is coated with an SCR formulation, ideally in the pores of the filter walls, so that the DPF and SCR functions can be combined into a single catalyst. Two state-of-the-art Cu/zeolite SCR formulations and three types of high porosity filter substrates were included in this study. Laboratory and engine-dynamometer tests were performed to measure NOx conversion under a variety of conditions to assess the impact of ammonia oxidation, inlet NO2/NOx ratio, ammonia/NOx ratio, oxygen level, space velocity, soot loading, and ammonia loading level.
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